 Van Freiheit (Flyheight)
Japanese seiyuu: NA
Pilot: Shield Liger/Blade Liger
Van is the main character of Zoids: Chaotic Century. He's still very young, but dreams of becoming a great zoids pilot like his father was before he died. Van lives with his sister in the Wind Colony village. He finds Zeke and Fiona inside a pair of capsules in an abandoned laboratory. After breaking them out, he befriends them and wants to help Fiona find Zoids Eve. Van has serious piloting potential and often times surprises even himself in battle.
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 Zeke
Japanese seiyuu: NA
Van's Organoid
Zeke is an organoid with very special abilities. When he fuses with Vans Shield Liger/Blade Liger he can give Van an enormous boost of strength. Zeke is the one who resurected the dead Shield Liger that was abandoned in the desert. Zeke is Van's best friend. Unlike most organoids, Zeke can make a zoid evolve into a much more powerful zoid.
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 Fiona
Japanese seiyuu: NA
Mysterious Girl
Fiona was found in a capsule right next to Zeke. She has no memory of herself other than something called Zoids Eve. She doesn't even know if Fiona is actually her name, but it's the first thing she said when Van asks. Whenever Fiona is near ancient Zoidian writing or artifacts she starts to see strange visions. Sometimes even pieces of her memory can come back. Theory has it that Fiona could be an ancient Zoidian herself.
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 Irvine
Japanese seiyuu: NA
Pilot: Command Wolf IS/Lightning Saix
Irvine is a mercenary. He isn't sided with anyone other than himself, but while he travels with Van he fights for the Republic. Irvine also likes to steal the things he wants. When he first meets Van, he tries to steal Zeke for himself, claiming that he's a worthless tool while in Van's posession. After fighting along side Van for a while, he eventually quits trying to steal Zeke, but always teases Van about it regardless. He has a softer side to him that he very rarely ever shows, but it's there nonetheless.
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 Moonbay
Japanese seiyuu: NA
Pilot: Gustav
Moonbay is a master Zoids mechanic. She can fix just about anything wrong with a zoid except a dead core. She's also a transporter, but after meeting Van the only things she transports are Van and Irvines zoids. Moonbay loves to sing as she travels. Sadly she could use a few more lessons but she won't admit it.
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 Dr. D
Japanese seiyuu: NA
Scientist: Republic
Dr. D is a scientific genious. He used to work for the Republic building new zoids and designing new zoids weaponry. Now in his old age he enjoys tagging along with Van and the gang helping them out where-ever he can. He even encourages them to "test" out weaponry and new zoids he's designed. Though Irvine would rather just steal it.
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 Madame President
Japanese seiyuu: NA
President: Republic
Madame President rules over the Helic Republic. She took over for her husband, the former President after he died. She does everything in her power to keep the Empire's forces from destroying the Republic Capital.
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 Robert Herman
Japanese seiyuu: NA
Captain: Republic
Captain Herman is the first one to teach Van about zoid combat. During a rescue attempt, they run into Raven who is always looking for a good fight. Herman is also the President's son.
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 Raven
Japanese seiyuu: NA
Pilot: Zaber Fang/Geno Saurer/Geno Breaker
Raven is a very skilled lone fighter for the Empire. He is ruthless when it comes to combat and will destroy any and all zoids that cross his path, whether they be friend or foe. He is always looking down on everyone and claiming that no one knows how to handle zoids. His organoid Shadow is always there to back him up when he finds himself in a difficult match.
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 Shadow
Japanese seiyuu: NA
Raven's Organoid
Shadow is Raven's black organoid. He looks alot like a robotic dragon, and only obeys Raven. Anyone else he will just thrash with his tail. Unlike Zeke, Shadow is not treated like a friend, but more like a tool.
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 Karl Lichen Schubaltz
Japanese seiyuu: NA
Major: Empire
Pilot: Dark Horn/Iron Kong
Schubaltz is a very wise soldier. He always keeps a cool head on his shoulders and can tell when the enemy is laying out a trap. He's very experianced in war, and although he doesn't agree on the war, he does his best to obey his orders while keeping the number of casualties minimal.
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 Rudolf Gerhard Zeppellin III
Japanese seiyuu: NA
Prince: Empire
Rudolf is the heir to the Empire's throne. His granfather, the emperor passed away leaving Rudolf in charge. Rudolf does not want the war that his grandfather begun to continue, and tries to make peace with the Republic.
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 Prozen
Japanese seiyuu: NA
Admiral: Empire
Prozen is the Empire's top Admiral. His goal is to defeat the Republic and claim their territory. However he only wants the prize for himself, and is determined to become the new emperor in place of Rudolf.
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 Rosso
Japanese seiyuu: NA
Dessert Alcavaledo Gang
Rosso is the leader of a desert gang of bandits known as the Dessert Alcavaledo Gang. He originally works for Prozen, but certain circumstances change that.
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 Viola
Japanese seiyuu: NA
Dessert Alcavaledo Gang
Viola is also a member of the Dessert Alcavaledo Gang. She fights alongside Rosso, going where-ever he does.
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